List of top Questions asked in JEE Advanced

Among the following complexes, the total number of diamagnetic species is ______.
[Mn(NH₃)₆]³⁺, [MnCl₆]³⁻, [FeF₆]³⁻, [CoF₆]³⁻, [Fe(NH₃)₆]³⁺, and [Co(en)₃]³⁺
[Given, atomic number: Mn = 25, Fe = 26, Co = 27;
en = H₂NCH₂CH₂NH₂]

In the following reaction sequence, the major product P is formed.

Glycerol reacts completely with excess P in the presence of an acid catalyst to form Q. Reaction of Q with excess NaOH followed by the treatment with CaCl₂ yields Ca-soap R, quantitatively. Starting with one mole of Q, the amount of R produced in gram is ______.
[Given, atomic weight: H = 1, C = 12, N = 14, O = 16, Na = 23, Cl = 35, Ca = 40]

Among V(CO)₆, Cr(CO)₅, Cu(CO)₃, Mn(CO)₅, Fe(CO)₅, [Co(CO)₃]^3-, [Cr(CO)₄]^4-, and Ir(CO)₃, the total number of species isoelectronic with Ni(CO)₄ is _________.
[Given, atomic number: V = 23, Cr=24, Mn 25, Fe 26, Co 27, Ni 28, Cu = 29, Ir = 77]

Complete reaction of acetaldehyde with excess formaldehyde, upon heating with conc. NaOH solution, gives P and Q. Compound P does not give Tollens' test, whereas Q on acidification gives positive Tollens' test. Treatment of P with excess cyclohexanone in the presence of catalytic amount of p-toluenesulfonic acid (PTSA) gives product R.
Sum of the number of methylene groups (-CH2-) and oxygen atoms in R is _______

Consider the following volume−temperature (V−T) diagram for the expansion of 5 moles of an ideal monoatomic gas.

Considering only P-V work is involved, the total change in enthalpy (in Joule) for the transformation of state in the sequence X→Y→Z is ______.
[Use the given data: Molar heat capacity of the gas for the given temperature range, C_V,_m = 12 J K⁻¹mol⁻¹ and gas constant, R=8.3 JK⁻¹ mol⁻¹]

Two large, identical water tanks, 1 and 2, kept on the top of a building of height H, are filled with water up to height ℎ in each tank. Both the tanks contain an identical hole of small radius on their sides, close to their bottom. A pipe of the same internal radius as that of the hole is connected to tank 2, and the pipe ends at the ground level. When the water flows from the tanks 1 and 2 through the holes, the times taken to empty the tanks are t1 and t2, respectively. If \(H = ( \frac{16}{ 9} ) ℎ\), then the ratio t1/t2 is ___

A source (S) of sound has frequency\( 240 Hz\). When the observer (O) and the source move towards each other at a speed \(v\) with respect to the ground (as shown in Case 1 in the figure), the observer measures the frequency of the sound to be \(288 Hz\). However, when the observer and the source move away from each other at the same speed v with respect to the ground (as shown in Case 2 in the figure), the observer measures the frequency of sound to be \(n\) Hz. The value of \(n\) is _____.

A disc of mass \(M\) and radius \(R\) is free to rotate about its vertical axis as shown in the figure. A battery operated motor of negligible mass is fixed to this disc at a point on its circumference. Another disc of the same mass \(M\) and radius \(R/2\) is fixed to the motor’s thin shaft. Initially, both the discs are at rest. The motor is switched on so that the smaller disc rotates at a uniform angular speed \(\omega\). If the angular speed at which the large disc rotates is \(\omega/n\), then the value of \(n\) is _____

The specific heat capacity of a substance is temperature dependent and is given by the formula C = kT, where k is a constant of suitable dimensions in SI units, and T is the absolute temperature. If the heat required to raise the temperature of 1 kg of the substance from −73 ° C to 27 ° C is nk, the value of n is ___[Given: 0 K = −273 °C.]

Let X be a random variable, and let P(X = x) denote the probability that X takes the value x. Suppose that the points (x, P(X = x)), x = 0,1,2,3,4, lie on a fixed straight line in the xy -plane, and P(X = x) = 0 for all x ∈ R - {0,1,2,3,4}. If the mean of X is \(\frac{5}{2}\) , and the variance of X is α, then the value of 24α is ______.

A group of 9 students, s₁, s₂,…., s₉, is to be divided to form three teams X, Y and Z of sizes 2, 3, and 4, respectively. Suppose that s₁ cannot be selected for the team X and s₂ cannot be selected for the team Y. Then the number of ways to form such teams, is _______.

Let \(S=\left\{\begin{pmatrix} 0 & 1 & c \\ 1 & a & d\\ 1 & b & e \end{pmatrix}:a,b,c,d,e\in\left\{0,1\right\}\ \text{and} |A|\in \left\{-1,1\right\}\right\}\), where |A| denotes the determinant of A. Then the number of elements in S is _______.

Let f(x) = x⁴ + ax³ + bx² + c be a polynomial with real coefficients such that f(1) = -9. Suppose that \(i\sqrt3\) is a root of the equation 4x³ + 3ax² + 2bx = 0, where\(i=\sqrt{-1}\) . If a₁, a₂, a₃ and a₄ are all the roots of the equation f(x) = 0, then |a₁|² + |a₂|² + |a₃|² + |a₄|² is equal to ______.

The compound(s) having peroxide linkage is(are)

The option(s) with correct sequence of reagents for the conversion of P to Q is(are)

An aqueous solution of hydrazine (N₂H₄) is electrochemically oxidized by O₂, thereby releasing chemical energy in the form of electrical energy. One of the products generated from the electrochemical reaction is N₂(g).
Choose the correct statement(s) about the above process

The species formed on fluorination of phosphorus pentachloride in a polar organic solvent are

In the following reaction sequence, the major product Q is
\(\text{L-Glucose}\xrightarrow[ii)Cr_2,775K,10-20 \text{atm}]{i)HI, \Delta}P\xrightarrow[UV]{Cl_2(excess)}Q\)

In a metal deficient oxide sample, M_XY₂O₄(M and Y are metals), M is present in both +2 and +3 oxidation states and Y is in +3 oxidation state. If the fraction of M²⁺ ions present in M is \(\frac{1}{3}\), the value of X is______.

According to Bohr’s model, the highest kinetic energy is associated with the electron in the

A positive, singly ionized atom of mass number \(A_M\) is accelerated from rest by the voltage \(192 V\). Thereafter, it enters a rectangular region of width 𝑤 with magnetic field \(\bar{B_0} = 0.1𝑘̂\)Tesla, as shown in the figure. The ion finally hits a detector at the distance 𝑥 below its starting trajectory. [Given: Mass of neutron/proton =\((5/3) × 10^{−27}\) kg, charge of the electron \(= 1.6 × 10^{−19} C.\)]

Which of the following option(s) is(are) correct?

A table tennis ball has radius \((3/2) × 10^{−2} \)m and mass \((22/7) × 10^{−3} \)kg. It is slowly pushed down into a swimming pool to a depth of 𝑑 = 0.7 m below the water surface and then released from rest. It emerges from the water surface at speed 𝑣, without getting wet, and rises up to a height 𝐻. Which of the following option(s) is(are) correct?[Given: \(\pi = 22/7, g = 10 m s ^{−2} \), density of water = \(1 × 10^3 kg\ m^{−3}\) , viscosity of water = \(1 × 10^{−3}\) Pa-s.] 

A small electric dipole \(\bar{P_0}\), having a moment of inertia I about its center, is kept at a distance r from the center of a spherical shell of radius R. The surface charge density \(\sigma\)is uniformly distributed on the spherical shell. The dipole is initially oriented at a small angle 𝜃 as shown in the figure. While staying at a distance r, the dipole is free to rotate about its center.If released from rest, then which of the following statement(s) is(are) correct?

If released from rest, then which of the following statement(s) is(are) correct?

A thin stiff insulated metal wire is bent into a circular loop with its two ends extending tangentially from the same point of the loop. The wire loop has mass 𝑚 and radius 𝑟 and it is in a uniform vertical magnetic field \(B_0\), as shown in the figure. Initially, it hangs vertically downwards, because of acceleration due to gravity 𝑔, on two conducting supports at P and Q. When a current 𝐼 is passed through the loop, the loop turns about the line PQ by an angle 𝜃 given by

 

A metal target with atomic number 𝑍 = 46 is bombarded with a high energy electron beam. The emission of X-rays from the target is analyzed. The ratio 𝑟 of the wavelengths of the 𝐾𝛼-line and the cut-off is found to be 𝑟 = 2. If the same electron beam bombards another metal target with 𝑍 = 41, the value of 𝑟 will be