Consider the following cell: $ \text{Pt}(s) \, \text{H}_2 (1 \, \text{atm}) | \text{H}^+ (1 \, \text{M}) | \text{Cr}_2\text{O}_7^{2-}, \, \text{Cr}^{3+} | \text{H}^+ (1 \, \text{M}) | \text{Pt}(s) $ Given: $ E^\circ_{\text{Cr}_2\text{O}_7^{2-}/\text{Cr}^{3+}} = 1.33 \, \text{V}, \quad \left[ \text{Cr}^{3+} \right]^2 / \left[ \text{Cr}_2\text{O}_7^{2-} \right] = 10^{-7} $ At equilibrium: $ \left[ \text{Cr}^{3+} \right]^2 / \left[ \text{Cr}_2\text{O}_7^{2-} \right] = 10^{-7} $ Objective: $ \text{Determine the pH at the cathode where } E_{\text{cell}} = 0. $
x mg of Mg(OH)$_2$ (molar mass = 58) is required to be dissolved in 1.0 L of water to produce a pH of 10.0 at 298 K. The value of x is ____ mg. (Nearest integer) (Given: Mg(OH)$_2$ is assumed to dissociate completely in H$_2$O)
Rate law for a reaction between $A$ and $B$ is given by $\mathrm{R}=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}$. If concentration of A is doubled and concentration of B is halved from their initial value, the ratio of new rate of reaction to the initial rate of reaction $\left(\frac{\mathrm{r}_{2}}{\mathrm{r}_{1}}\right)$ is
The shortest distance between the curves $ y^2 = 8x $ and $ x^2 + y^2 + 12y + 35 = 0 $ is:
Let $ \vec{a} = \hat{i} + 2\hat{j} + \hat{k} $, $ \vec{b} = 3\hat{i} - 3\hat{j} + 3\hat{k} $, $ \vec{c} = 2\hat{i} - \hat{j} + 2\hat{k} $ and $ \vec{d} $ be a vector such that $ \vec{b} \times \vec{d} = \vec{c} \times \vec{d} $ and $ \vec{a} \cdot \vec{d} = 4 $. Then $ |\vec{a} \times \vec{d}|^2 $ is equal to _______
Let \( A = \begin{bmatrix} \alpha & -1 \\ 6 & \beta \end{bmatrix} , \ \alpha > 0 \), such that \( \det(A) = 0 \) and \( \alpha + \beta = 1. \) If \( I \) denotes the \( 2 \times 2 \) identity matrix, then the matrix \( (I + A)^8 \) is:
Let \( a \in \mathbb{R} \) and \( A \) be a matrix of order \( 3 \times 3 \) such that \( \det(A) = -4 \) and \[ A + I = \begin{bmatrix} 1 & a & 1 \\ 2 & 1 & 0 \\ a & 1 & 2 \end{bmatrix} \] where \( I \) is the identity matrix of order \( 3 \times 3 \).
If \( \det\left( (a + 1) \cdot \text{adj}\left( (a - 1) A \right) \right) \) is \( 2^m 3^n \), \( m, n \in \{ 0, 1, 2, \dots, 20 \} \), then \( m + n \) is equal to:
If the sum of the first 10 terms of the series \[ \frac{4 \cdot 1}{1 + 4 \cdot 1^4} + \frac{4 \cdot 2}{1 + 4 \cdot 2^4} + \frac{4 \cdot 3}{1 + 4 \cdot 3^4} + \ldots \] is \(\frac{m}{n}\), where \(\gcd(m, n) = 1\), then \(m + n\) is equal to _____.
Which of the following circuits has the same output as that of the given circuit?