Observe the following solutions
\[
\text{I. Black coffee} \quad \text{II. 0.2M NaOH} \quad \text{III. Lemon juice} \quad \text{IV. Lime water} \quad \text{V. Human Saliva} \quad \text{VI. Tomato juice}
\]
The number of solutions having pH range of 1-7 and 7-14, in the above list, is respectively