pH is a measure of the acidity or basicity of a solution. A pH value of 7 indicates a neutral solution. Solutions with pH less than 7 are acidic, while those with pH greater than 7 are basic.
Let's analyze the pH of each solution:
- I. Black coffee – Black coffee is mildly acidic with a pH between 5 and 6.
- II. 0.2M NaOH – Sodium hydroxide is a strong base with a pH greater than 7 (around 13).
- III. Lemon juice – Lemon juice is acidic with a pH around 2 to 3.
- IV. Lime water – Lime water is slightly basic with a pH around 12.
- V. Human Saliva – Human saliva is slightly acidic with a pH around 6.5.
- VI. Tomato juice – Tomato juice is acidic with a pH around 4 to 5.
Thus, the solutions with pH less than 7 are:
- Black coffee (acidic)
- Lemon juice (acidic)
- Human Saliva (slightly acidic)
- Tomato juice (acidic)
Therefore, the number of solutions with pH less than 7 is 4.
Thus, the correct answer is \( \boxed{4} \).