We are given a 5 m aqueous solution, meaning there are 5 moles of solute dissolved in 1 kg of solvent (water).
To calculate the mole fraction of solute, we use the following formula:
\[
\text{Mole fraction of solute} = \frac{\text{Moles of solute}}{\text{Moles of solute} + \text{Moles of solvent}}
\]
For 1 kg of water, the number of moles of solvent (water) is:
\[
\text{Moles of water} = \frac{\text{Mass of water}}{\text{Molar mass of water}} = \frac{1000 \, \text{g}}{18 \, \text{g/mol}} = 55.56 \, \text{mol}
\]
Now, the mole fraction of solute is:
\[
\text{Mole fraction of solute} = \frac{5 \, \text{mol}}{5 \, \text{mol} + 55.56 \, \text{mol}} = \frac{5}{60.56} = 0.082
\]
Thus, the mole fraction of the solute is 0.082.