- Solutions with pH in the range 1-7 are acidic.
- Solutions with pH in the range 7-14 are basic (alkaline).
\begin{itemize}
\item I. Black coffee is mildly acidic with a pH of around 5, so it falls in the 1-7 range.
\item II. 0.2M NaOH is a strong base, so it falls in the 7-14 range.
\item III. Lemon juice is acidic with a pH of around 2, so it falls in the 1-7 range.
\item IV. Lime water is basic with a pH around 12, so it falls in the 7-14 range.
\item V. Human saliva is slightly acidic with a pH around 6, so it falls in the 1-7 range.
\item VI. Tomato juice is slightly acidic with a pH of around 4, so it falls in the 1-7 range.
\end{itemize}
Thus, the number of solutions having pH range 1-7 is 4 (Black coffee, Lemon juice, Human Saliva, Tomato juice), and the number of solutions having pH range 7-14 is 2 (0.2M NaOH, Lime water).
Thus, the correct answer is option (4) 4, 2.