$\Delta_{r} G^{\circ}$ at $500 \,K$ for substance 'S' in liquid state and gascous state are $+100.7 \,kcal\, mol ^{-1} $ and $+103 \,kcal \,mol ^{-1}$, respectively. Vapour pressure of liquid ' S ' at $500\, K$ is approximately equal to $\left(R=2 \,cal K ^{-1} \,mol ^{-1}\right)$