Question:

Lithium nitrate and sodium nitrate, when heated separately, respectively, give :

Updated On: Dec 29, 2025
  • LiNO2 and NaNO2

  • Li2O and Na2O

  • Li2O and NaNO2

  • LiNO2 and Na2O

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The Correct Option is C

Approach Solution - 1

When lithium nitrate (LiNO3) and sodium nitrate (NaNO3) are heated, they decompose into different products due to their distinct positions in the periodic table and chemical reactivity. 

  1. For lithium nitrate:
    • The decomposition reaction of lithium nitrate is as follows:

\(2\text{LiNO}_{3(s)} \rightarrow \text{Li}_{2}\text{O}_{(s)} + 2\text{NO}_{2(g)} + \frac{1}{2}\text{O}_{2(g)}\)

  • This reaction indicates that lithium nitrate decomposes to form lithium oxide (Li2O), nitrogen dioxide (NO2), and oxygen (O2) gases upon heating.
  1. For sodium nitrate:
    • The decomposition reaction of sodium nitrate is as follows:

\(2\text{NaNO}_{3(s)} \rightarrow 2\text{NaNO}_{2(s)} + \text{O}_{2(g)}\)

  • This reaction shows that sodium nitrate decomposes to form sodium nitrite (NaNO2) and oxygen (O2). Sodium nitrite is a solid compound.

Therefore, the correct answer is that upon heating, lithium nitrate gives lithium oxide (Li2O) and sodium nitrate gives sodium nitrite (NaNO2).

Conclusion: The correct option is Li2O and NaNO2.

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Approach Solution -2

On heating, lithium nitrate produces lithium oxide (Li2O), while sodium nitrate yields sodium nitrite.
4LiNO3→ 2Li2O + 4NO2 + O2
2NaNO3→ 2NaNO2 + O2
So, the correct option is (C): Li2O and NaNO2

 

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Concepts Used:

S-Block Elements

S-block elements, also known as alkali and alkaline earth metals, constitute the first two groups of the periodic table.

Group 1 elements, including hydrogen, lithium, sodium, potassium, rubidium, cesium, and francium, are alkali metals characterized by low density, high reactivity, and the ability to form strong bases when combined with water. They showcase a single valence electron in their outermost shell, making them eager to lose it in chemical reactions.

Group 2 elements, beryllium, magnesium, calcium, strontium, barium, and radium, make up the alkaline earth metals in Group 2. These metals share similar properties, such as higher densities and melting points compared to alkali metals. They also have a tendency to form ionic compounds with nonmetals.

S-block elements play vital roles in various industrial and biological processes. Alkali metals find applications in batteries, while alkaline earth metals are crucial for construction materials and are essential nutrients for living organisms. Despite their importance, the reactivity of alkali metals requires careful handling, often stored in oil to prevent reactions with moisture or oxygen. Overall, s-block elements contribute significantly to the diverse applications of chemistry in our daily lives.