From the magnetic behaviour of \([NiCl_4]^{2-}\) (paramagnetic) and [Ni\((CO)_4\)] (diamagnetic), choose the correct geometry and oxidation state.

Arrange the following solutions in order of their increasing boiling points.
(i) \(10^{-4}\) M NaCl
(ii) \(10^{-4}\) M Urea
(iii) \(10^{-3}\) M NaCl
(iv) \(10^{-2}\) M NaCl

The IUPAC name of the following compound is:

Some CO\(_2\) gas was kept in a sealed container at a pressure of 1 atm and at 273 K. This entire amount of CO\(_2\) gas was later passed through an aqueous solution of Ca(OH)\(_2\). The excess unreacted Ca(OH)\(_2\) was later neutralized with 0.1 M of 40 mL HCl. If the volume of the sealed container of CO\(_2\) was \(x\), then \(x\) is ________________________ cm\(^3\) (nearest integer). [Given: The entire amount of CO\(_2\) reacted with exactly half the initial amount of Ca(OH)\(_2\) present in the aqueous solution.]

The molecule A changes into its isomeric form B by following a first order kinetics at a temperature of 1000 K. If the energy barrier with respect to reactant energy for such isomeric transformation is 191.48 kJ mol\(^{-1}\) and the frequency factor is \(10^{20}\), the time required for 50\% molecules of A to become B is ________________________ picoseconds (nearest integer). [R = 8.314 J K\(^{-1}\) mol\(^{-1}\)]

A liquid when kept inside a thermally insulated closed vessel at \(25^{\circ}C\) was mechanically stirred from outside. What will be the correct option for the following thermodynamic parameters?

Radius of the first excited state of Helium ion is given as:
\(a_0\) = radius of first stationary state of hydrogen atom.

Electrolysis of 600 mL aqueous solution of NaCl for 5 min changes the pH of the solution to 12. The current in Amperes used for the given electrolysis is ________________________. (Nearest integer).

Lanthanoid ions with \(4f^7\) configuration are: (A) Eu\(^{2+}\) (B) Gd\(^{3+}\) (C) Eu\(^{3+}\) (D) Tb\(^{3+}\) (E) Sm\(^{2+}\) Choose the correct answer from the options given below:

The number of molecules/ions that show linear geometry among the following is _____. SO₂, BeCl₂, CO₂, N₃⁻, NO₂, F₂O, XeF₂, NO₂⁺, I₃⁻, O₃

The incorrect statements regarding geometrical isomerism are:
(A) Propene shows geometrical isomerism.
(B) Trans isomer has identical atoms/groups on the opposite sides of the double bond.
(C) Cis-but-2-ene has higher dipole moment than trans-but-2-ene.
(D) 2-methylbut-2-ene shows two geometrical isomers.
(E) Trans-isomer has lower melting point than cis isomer.

How many different stereoisomers are possible for the given molecule?

Given below are two statements: Statement I: One mole of propyne reacts with excess of sodium to liberate half a mole of H₂ gas. Statement II: Four g of propyne reacts with NaNH₂ to liberate NH₃ gas which occupies 224 mL at STP. In the light of the above statements, choose the most appropriate answer from the options given below:

Match List-I with List-II:

In Carius method for estimation of halogens, 180 mg of an organic compound produced 143.5 mg of AgCl. The percentage composition of chlorine in the compound is ___________%. [Given: Molar mass in g mol\(^{-1}\) of Ag = 108, Cl = 35.5]

What is the shape of the \( \text{ClO}_2^- \) ion according to VSEPR theory?