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Chemistry
List of top Chemistry Questions
Write the chemical equation for the reactions of chlorine with (i) sulphur dioxide, and (ii) turpentine oil.
UP Board XII - 2023
UP Board XII
Chemistry
Inorganic chemistry
When a copper rod is dipped into silver nitrate solution, why does the colour of the solution turn blue? Explain.
UP Board XII - 2023
UP Board XII
Chemistry
Redox Reactions
How many primary alcoholic groups are present in glucose?
UP Board XII - 2023
UP Board XII
Chemistry
Carbohydrates
69.77% Carbon, 11.63% Hydrogen and the rest Oxygen is present in an organic compound. The molecular mass of the compound is 86. The compound does not reduce Tollen’s reagent but gives an addition compound with sodium hydrogen sulphite and gives positive iodoform test. On strong oxidation it gives ethanoic acid and propanoic acid. Write the structure of possible compound.
UP Board XII - 2023
UP Board XII
Chemistry
Organic Chemistry
On Cannizzaro’s reaction formaldehyde forms:
UP Board XII - 2023
UP Board XII
Chemistry
Aldehydes And Ketones
R–NH$_2$ + CHCl$_3$ + 3KOH (alc.) $\longrightarrow$ RNC + 3KCl + 3H$_2$O. The above reaction is:
UP Board XII - 2023
UP Board XII
Chemistry
Organic Chemistry
How many moles of water are present in 180 g of water?
UP Board XII - 2023
UP Board XII
Chemistry
Mole concept and Molar Masses
Potassium sulphate is:
UP Board XII - 2023
UP Board XII
Chemistry
Inorganic chemistry
Write short notes on the following:
(i) Claisen Reaction
(ii) Cannizzaro’s Reaction
(iii) Rosenmund’s Reaction
UP Board XII - 2023
UP Board XII
Chemistry
carbonyl compounds
The rate constant of a reaction A + 2B $\longrightarrow$ Product is expressed by the equation $R = [A][B]^2$. The molecularity of reaction will be:
UP Board XII - 2023
UP Board XII
Chemistry
Chemical Kinetics
In the reaction 2A $\longrightarrow$ Products, concentration of A decreases from 0.5 mol L$^{-1
$ to 0.4 mol L$^{-1}$ in 10 minutes. Find the rate of reaction during the time interval.}
UP Board XII - 2023
UP Board XII
Chemistry
Theories of reaction rates
What happens when (Write chemical equations only):
(i) \textit{n}-Butyl chloride reacts with alcoholic KOH?
(ii) Bromobenzene reacts with magnesium in the presence of dry ether?
(iii) Ethyl chloride reacts with aqueous KOH?
(iv) Methyl bromide reacts with sodium in the presence of dry ether?
(v) Ethyl bromide reacts with KCN (alc.)?
UP Board XII - 2023
UP Board XII
Chemistry
Organic Chemistry
For the reaction $N_2O_5 \longrightarrow 2NO_2 + \tfrac{1
{2}O_2$, if} \[ -\frac{d[N_2O_5]}{dt} = K'[N_2O_5], \quad \frac{d[NO_2]}{dt} = K''[N_2O_5], \quad \frac{d[O_2]}{dt} = K'''[N_2O_5] \]
then establish the relation between $K'$, $K''$, and $K'''$.
UP Board XII - 2023
UP Board XII
Chemistry
Stoichiometry and Stoichiometric Calculations
An aromatic organic compound A on treatment with aqueous ammonia and heating forms compound B, which on heating with Br$_2$ and KOH forms a compound C of molecular formula C$_6$H$_7$N. Write the structures and names of compounds A, B and C.
UP Board XII - 2023
UP Board XII
Chemistry
Aromaticity & chemistry of aromatic compounds
Write short notes on:
(i) Williamson’s ether synthesis
(ii) Fermentation
(iii) To obtain methyl alcohol from pyroligneous acid
UP Board XII - 2023
UP Board XII
Chemistry
Organic Chemistry
How will you convert chlorobenzene into the following? (Write chemical equations only)
(i) Benzene
(ii) Phenol
(iii) Toluene
(iv) Aniline
(v) Diphenyl
UP Board XII - 2023
UP Board XII
Chemistry
Aromaticity & chemistry of aromatic compounds
An aromatic organic compound A yields B and C when it reacts with CHCl$_3$ and KOH. On distillation with Zn dust, D is formed. On oxidation, D yields compound E having molecular formula C$_7$H$_6$O$_2$. Identify A, B, C, D and E. Write the chemical equation of each reaction also.
UP Board XII - 2023
UP Board XII
Chemistry
Phenols
For the reaction 2A + B $\longrightarrow$ 2C + 3D, the rate of change in concentration of C is 1.0 mol L$^{-1
$ s$^{-1}$. Find the rate of reaction and rate of change in concentration of A, B and D.}
UP Board XII - 2023
UP Board XII
Chemistry
Chemical Kinetics
A reaction is of first order with respect to a reactant. How is the rate of reaction affected, if the concentration of the reactant is doubled?
UP Board XII - 2023
UP Board XII
Chemistry
Chemical Kinetics
Ketones do not reduce Fehling’s solution and Tollen’s reagent, while fructose containing ketonic group does. Why?
UP Board XII - 2023
UP Board XII
Chemistry
carbonyl compounds
Using IUPAC norms, write the systematic names of the following:
(i) [Co(NH$_3$)$_6$]Cl$_3$
(ii) K$_3$[Cr(C$_2$O$_4$)$_3$]
(iii) [Pt(NH$_3$)$_2$Cl$_2$]
(iv) [Ni(CO)$_4$]
UP Board XII - 2023
UP Board XII
Chemistry
Coordination Compounds
Differentiate between molar and molal elevation constants. Give two different formulae involving these two constants for the determination of molecular mass of solute.
UP Board XII - 2023
UP Board XII
Chemistry
Colligative Properties
Classify each of the following solids as ionic, metallic and molecular: P$_4$, Ammonium phosphate, Brass, Tetraphosphorus decoxide (P$_4$O$_{10}$), Rb, I$_2$, LiBr
UP Board XII - 2023
UP Board XII
Chemistry
Properties of Solids
Prove the presence of five –OH groups and a –CHO group in glucose molecule, giving chemical equations. How is silver mirror formed from glucose?
UP Board XII - 2023
UP Board XII
Chemistry
Organic Chemistry
Explain with reason:
(i) The colloidal solution of Fe(OH)$_3$ obtained from FeCl$_3$ is positively charged.
(ii) Alum is used for the purification of water.
(iii) Rivers form a delta while joining a sea/ocean.
UP Board XII - 2023
UP Board XII
Chemistry
Colloids
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