Write I.U.P.A.C. names of the following:
(i) \([Co(NH_3)_6]Cl_3\)
(ii) \([Ti(H_2O)_6]^{3+}\)
(iii) \( K_2[Ni(CN)_4] \)
(iv) \([Pt(NH_3)_2Cl_2]\)
Step 1: Identify the ligands, oxidation state, and coordination number.
Step 2: The correct IUPAC names are:
(i) Hexaamminecobalt(III) chloride
(ii) Hexaaquatitanium(III) ion
(iii) Potassium tetracyanonickelate(II)
(iv) Diammine dichloroplatinum(II)
Give the structures of A, B, and C in the following reaction sequences:
(i) \(\mathrm{CH_3CH_2I} \xrightarrow[\ ]{\mathrm{NaCN}} A \xrightarrow[\ ]{\;\;HO^-\;/\;H_2O\;\;} B \xrightarrow[\;Br_2/NaOH\;]{} C\)
(ii) \(\mathrm{C_6H_5N_2^+Cl^-} \xrightarrow[\ ]{\mathrm{CuCN}} A \xrightarrow[\ ]{\;H_3O^+\;} B \xrightarrow[\ \Delta\ ]{\;NH_3\;} C\)
(iii) \(\mathrm{CH_3CH_2Br} \xrightarrow[\ ]{\mathrm{KCN}} A \xrightarrow[\ ]{\mathrm{LiAlH_4}} B \xrightarrow[\;273\,K\;]{\;HNO_2\;} C\)
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