Question:

Two moles of helium are mixed with $n$ moles of hydrogen. If $\frac{C_P}{C_V} = \frac{3}{2}$ for the mixture, then the value of n is :

Updated On: Jul 13, 2024
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The Correct Option is C

Solution and Explanation

For mixture of gases, we have $\frac{\left(n_{1}+n_{2}\right)}{(\gamma-1)}=\frac{n_{1}}{\left(\gamma_{1}-1\right)}+\frac{n_{2}}{\left(\gamma_{2}-1\right)}$ ...(1) Given: $n_{1}=2$ (for helium); $\gamma=\frac{3}{2}$. Since, $f=3$ for monatomic gas and $f=5$ for diatomic gas. Therefore, $\gamma_{1}=\left(1+\frac{2}{f}\right)=\left(1+\frac{2}{3}\right)=\frac{5}{3}$ $\Rightarrow \gamma_{2}=\left(1+\frac{2}{5}\right)=\frac{7}{5}$ where $f$ is number of degrees of freedom. Now, substitute $n_{2}=n$ in E (1), we get $\frac{(2+n)}{\left(\frac{3}{2}-1\right)}=\frac{2}{\left(\frac{5}{3}-1\right)}+\frac{n}{\left(\frac{7}{5}-1\right)}$ $\frac{(2+n)}{1 / 2}=\frac{2}{2 / 3}+\frac{n}{2 / 5}$ $\Rightarrow 2(2+n) =3+\frac{5}{2} n$ $4+2 n=3+2.5 n$ $\Rightarrow 0.5 n=1$ $\Rightarrow n=2$
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Concepts Used:

Specific Heat Capacity

Specific heat of a solid or liquid is the amount of heat that raises the temperature of a unit mass of the solid through 1°C.

Molar Specific Heat:

The Molar specific heat of a solid or liquid of a material is the heat that you provide to raise the temperature of one mole of solid or liquid through 1K or 1°C. 

Specific Heat at Constant Pressure or Volume:

The volume of solid remains constant when heated through a small range of temperature. This is known as specific heat at a constant volume. It is denoted as CV.

The pressure of solid remains constant when heated through a small range of temperature. This is known as specific heat at constant pressure which can be denoted as CP.