List of practice Questions

What happens when glucose reacts with bromine water? Write the chemical equation.
Write the electronic configuration for d$^4$ ion if \( \Delta_0 < P \) on the basis of crystal field theory.
Assertion (A): p-nitrophenol is less acidic than phenol.
Reason (R): Nitro group is electron-withdrawing and helps in the stabilization of p-nitrophenoxide ion.
Assertion (A): Benzoic acid does not undergo Friedel – Crafts reaction.
Reason (R): Carboxyl group is deactivating and the catalyst aluminium chloride gets bonded to the carboxyl group.
Assertion (A): Fructose is a reducing sugar.
Reason (R): Fructose does not reduce Fehling solution and Tollen’s reagent.
Assertion (A): For a Daniell cell, Zn/Zn$^{2+}$(1M) || Cu$^{2+}$(1M)/Cu with \( E_{\text{cell}} = 1.1 \, V \), if the external opposing potential is more than 1.1 V, the electrons flow from Cu to Zn.
Reason (R): Cell acts like a galvanic cell.
Define the following terms:
(a) Order of Reaction:
(b) Activation Energy:
Match the reagents required for the given reactions: I. Oxidation of primary alcohols to aldehydes (p) \(NaBH_4\)
II. Butan-2-one to Butan-2-ol (q) 85% phosphoric acid at 440 K
III. Bromination of Phenol to 2, 4, 6- (r) PCC Tribromophenol
IV. Dehydration of propan-2-ol to (s) Bromine water propene
The general electronic configuration of d-block elements is:
An 18-year-old male had a severe dislike for touching door knobs. He feared contamination and spent hours washing his hands if he had to open a door at his office. He spent more than 3-4 hours taking a shower and spent a lot of time cleaning surfaces after "incidental contaminations." Eventually, he stopped waking up in the morning as it was not worth the effort. Identify the disorder he is suffering from:
The Valence Bond Theory (VBT) explains the formation, magnetic behaviour and geometrical shapes of coordination compounds whereas ’The Crystal Field Theory’ for coordination compounds is based on the effect of different crystal fields (provided by ligands taken as point charges), on the degeneracy of d-orbital energies of the central metal atom/ion. The splitting of the d-orbitals provides different electronic arrangements in strong and weak crystal fields. The crystal field theory attributes the colour of the coordination compounds to d-d transition of the electron. Coordination compounds find extensive applications in metallurgical processes, analytical and medicinal chemistry.
Answer the following questions:
Write the structures of A and B in the following reaction: \[ \text{C}_6\text{H}_5\text{COOH} \xrightarrow{\text{NH}_3, \Delta} A \xrightarrow{\text{Br}_2/\text{NaOH}} B \]
Write a simple chemical test to distinguish between methylamine and aniline.
Write the chemical reaction involved in Gabriel phthalimide synthesis.
How will you convert aniline to p-bromoaniline?
Complete the following reaction: \[ \text{C}_6\text{H}_5\text{N}_2^+Cl^- \xrightarrow{\text{(i) HBF}_4} \xrightarrow{\text{(ii) NaNO}_2/\text{Cu}, \Delta} \quad ? \]
Why are equimolar solutions of sodium chloride and glucose not isotonic?
Out of chlorobenzene and 2,4,6-trinitrochlorobenzene, which is more reactive towards nucleophilic substitution and why?
Assertion (A): Transition metals have high enthalpy of atomization. Reason (R): This is because transition metals have low melting points.
Assertion (A): When NaCl is added to water, elevation in boiling point is observed. Reason (R): Elevation in boiling point is a colligative property.
Draw the structures of major monohalo products in each of the following reactions:
monohalo products
Phenol on reaction with aqueous bromine at room temperature gives:
The specific sequence in which amino acids are arranged in a protein is called:
Assertion (A): The pK$_a$ of O$_2$N–CH$_2$–COOH is lower than that of CH$_3$–COOH. Reason (R): The –NO$_2$ group shows an electron-withdrawing effect, which increases the acidic character of O$_2$N–CH$_2$–COOH.
Decarboxylation of sodium benzoate on heating with soda lime gives: