An ideal gas initially at 0°C temperature, is compressed suddenly to one fourth of its volume. If the ratio of specific heat at constant pressure to that at constant volume is \( \frac{3}{2} \), the change in temperature due to the thermodynamics process is K.
To determine the temperature change during an adiabatic compression of an ideal gas, we follow these steps:
1. Initial Conditions:
- Initial temperature (T₁) = 0°C = 273 K
- Initial volume (V₁)
- Final volume (V₂) = V₁/4
- Ratio of specific heats (γ) = Cₚ/Cᵥ = 3/2
2. Adiabatic Process Relation:
For an adiabatic process, we use:
\[
T V^{\gamma - 1} = \text{constant}
\]
Which gives the relation:
\[
T_1 V_1^{\gamma - 1} = T_2 V_2^{\gamma - 1}
\]
3. Calculate Final Temperature:
Solving for the final temperature T₂:
\[
T_2 = T_1 \left( \frac{V_1}{V_2} \right)^{\gamma - 1} = 273 \left( \frac{V_1}{V_1/4} \right)^{1/2} = 273 \times (4)^{1/2} = 273 \times 2 = 546 \text{ K}
\]
4. Determine Temperature Change:
The change in temperature is:
\[
\Delta T = T_2 - T_1 = 546 \text{ K} - 273 \text{ K} = 273 \text{ K}
\]
Key Points:
- The process is adiabatic (no heat transfer)
- Volume reduces to 1/4th of original
- Temperature doubles due to the compression
- γ = 3/2 indicates a monatomic ideal gas
Final Answer:
The temperature increases by \(\boxed{273 \text{ K}}\).
The standard enthalpy and standard entropy of decomposition of \( N_2O_4 \) to \( NO_2 \) are 55.0 kJ mol\(^{-1}\) and 175.0 J/mol respectively. The standard free energy change for this reaction at 25°C in J mol\(^{-1}\) is (Nearest integer)
Match the List-I with List-II
Choose the correct answer from the options given below:
The effect of temperature on the spontaneity of reactions are represented as: Which of the following is correct?
A gun fires a lead bullet of temperature 300 K into a wooden block. The bullet having melting temperature of 600 K penetrates into the block and melts down. If the total heat required for the process is 625 J, then the mass of the bullet is grams. Given Data: Latent heat of fusion of lead = \(2.5 \times 10^4 \, \text{J kg}^{-1}\) and specific heat capacity of lead = 125 J kg\(^{-1}\) K\(^{-1}\).