A gun fires a lead bullet of temperature 300 K into a wooden block. The bullet having melting temperature of 600 K penetrates into the block and melts down. If the total heat required for the process is 625 J, then the mass of the bullet is grams. Given Data: Latent heat of fusion of lead = \(2.5 \times 10^4 \, \text{J kg}^{-1}\) and specific heat capacity of lead = 125 J kg\(^{-1}\) K\(^{-1}\).
To solve this problem, we need to calculate the mass of the bullet that melts upon heating. We are given the following data:
The problem involves two main heat processes:
The total heat required can be divided into two parts:
The total heat \(Q\) is given by the sum of \(Q_1\) and \(Q_2\):
\(Q = mc (T_m - T_i) + mL\)
Substituting the known values:
\(625 = m \times 125 \times (600 - 300) + m \times 2.5 \times 10^4\)
Simplifying this equation:
\(625 = m \times (125 \times 300 + 2.5 \times 10^4)\)
\(625 = m \times (37500 + 25000)\)
\(625 = m \times 62500\)
Solving for \(m\):
\(m = \frac{625}{62500} = \frac{1}{100} \ \text{kg} = 0.01 \ \text{kg} = 10 \ \text{g}\)
Thus, the mass of the bullet is 10 grams.
The effect of temperature on the spontaneity of reactions are represented as: Which of the following is correct?

Match the List-I with List-II

Choose the correct answer from the options given below:
Using the given P-V diagram, the work done by an ideal gas along the path ABCD is: 
For a given reaction \( R \rightarrow P \), \( t_{1/2} \) is related to \([A_0]\) as given in the table. Given: \( \log 2 = 0.30 \). Which of the following is true?
| \([A]\) (mol/L) | \(t_{1/2}\) (min) |
|---|---|
| 0.100 | 200 |
| 0.025 | 100 |
A. The order of the reaction is \( \frac{1}{2} \).
B. If \( [A_0] \) is 1 M, then \( t_{1/2} \) is \( 200/\sqrt{10} \) min.
C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M.
D. \( t_{1/2} \) is 800 min for \( [A_0] = 1.6 \) M.