One of the Maxwell equations is expressed as
\(\left( \dfrac{\partial s}{\partial v} \right)_{T = \left( \dfrac{\partial p}{\partial T} \right)_{v}\),
where \(s\) is the entropy per unit mass, \(v\) is the mass specific volume, \(p\) is the pressure, and \(T\) is the temperature.
In this expression, \(s\) is a continuous function of \(T\) and \(v\). Let \(c_v\) be the specific heat capacity at constant volume for a gas.
Then, \(\left( \dfrac{\partial c_v}{\partial v} \right)_{T}\) can be written as}