For an ideal gas, the relation between the heat capacities at constant pressure (\(C_P\)) and constant volume (\(C_V\)) is given by: \[ C_P - C_V = R \] where \( R \) is the universal gas constant. Therefore, the correct relation between \( C_P \) and \( C_V \) is: \[ C_P = C_V + R \]
The correct option is (B) : \(C_p=C_v+R\)
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: