Question:

Two solutions $A$ and $B$ are prepared by dissolving $1 g$ of non-volatile solutes $X$ and $Y$ respectively in $1 \,kg$ of water The ratio of depression in freezing points for $A$ and $B$ is found to be $1: 4$ The ratio of molar masses of $X$ and $Y$ is :

Updated On: May 8, 2025
  • $1: 4$
  • $1: 0.25$
  • $1: 0.20$
  • $1: 5$
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The Correct Option is B

Solution and Explanation

\(\frac{​Δ_Tf_x}{Δ_Tf_y}​​=\frac{​k_f​⋅mx}{k_f​⋅my}​​=\frac{\frac{1/M_x}{1}}{\frac{1/M_y}{1}}\)​​​ 

\(⇒\frac{1}{4}​=\frac{​M_y}{M_x}​​ \)

\(⇒M_x​:M_y​=1:0.25\)

\(\text{Hence, the correct option (B):} 1:0.25\)

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Concepts Used:

Solutions

A solution is a homogeneous mixture of two or more components in which the particle size is smaller than 1 nm.

For example, salt and sugar is a good illustration of a solution. A solution can be categorized into several components.

Types of Solutions:

The solutions can be classified into three types:

  • Solid Solutions - In these solutions, the solvent is in a Solid-state.
  • Liquid Solutions- In these solutions, the solvent is in a Liquid state.
  • Gaseous Solutions - In these solutions, the solvent is in a Gaseous state.

On the basis of the amount of solute dissolved in a solvent, solutions are divided into the following types:

  1. Unsaturated Solution- A solution in which more solute can be dissolved without raising the temperature of the solution is known as an unsaturated solution.
  2. Saturated Solution- A solution in which no solute can be dissolved after reaching a certain amount of temperature is known as an unsaturated saturated solution.
  3. Supersaturated Solution- A solution that contains more solute than the maximum amount at a certain temperature is known as a supersaturated solution.