Question:

Quantitative analysis of an organic compound (X) shows the following percentage composition. 
C: 14.5% 
Cl: 64.46% 
H: 1.8% 
Empirical formula mass of the compound (X) is:

Updated On: Apr 30, 2025
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Correct Answer: 1655

Solution and Explanation

Element% MassMolar RatioSimplest Ratio
C14.5$ \frac{14.5}{12} = 1.2 $$ \frac{1.2}{1.2} = 1 $
Cl64.46$ \frac{64.46}{35.5} \approx 1.8 $$ \frac{1.8}{1.2} = 1.5 $
H1.8$ \frac{1.8}{1} = 1.8 $$ \frac{1.8}{1.2} = 1.5 $
O19.24$ \frac{19.24}{16} \approx 1.2 $$ \frac{1.2}{1.2} = 1 $

Steps:

  1. Divide % composition by atomic mass to get molar ratio.
  2. Divide each ratio by the smallest value to get simplest ratio.
  3. Multiply all ratios by a factor to convert to whole numbers if necessary.

Empirical Formula: $ C_2H_3Cl_3O_2 $

Molar Mass: $ 165.5\,\text{g/mol} $ (or $ 1655 \times 10^{-1}\,\text{g/mol} $)

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