Question

Density of 3 M NaCl solution is 1.25 g/mL. The molality of the solution is:

• A. 2.79 m
• B. 1.79 m
• C. 3 m
• D. 2 m

Hint:

To calculate molality, remember that molality is based on the mass of the solvent in kilograms, not the volume of the solution.

Answer 1

The Correct Option is C

We are given: - Molarity (M) = 3 M (mol/L) - Density of solution = 1.25 g/mL = 1250 g/L The molality (m) is given by the formula: \[ m = \frac{\text{moles of solute}}{\text{kg of solvent}} \] From molarity, the number of moles of NaCl in 1 liter of solution is: \[ \text{moles of NaCl} = 3 \, \text{mol} \] To find the mass of NaCl, use the molar mass of NaCl (58.44 g/mol): \[ \text{mass of NaCl} = 3 \, \text{mol} \times 58.44 \, \text{g/mol} = 175.32 \, \text{g} \] Now, the mass of the solvent (water) is: \[ \text{mass of solvent} = 1250 \, \text{g} - 175.32 \, \text{g} = 1074.68 \, \text{g} = 1.07468 \, \text{kg} \] Thus, the molality is: \[ m = \frac{3 \, \text{mol}}{1.07468 \, \text{kg}} = 2.79 \, \text{m} \] Therefore, the correct answer is 2.79 m.