Let \( w_1 \) and \( w_2 \) be the points obtained by the rotations of the complex numbers \( z_1 = 5 + 4i \) and \( z_2 = 3 + 5i \), respectively.
We are asked to find the principal argument of \( w_1 - w_2 \).
For \( w_1 \), the rotation is anticlockwise by \( 90^{\circ} \). The rotation of a complex number \( z = x + yi \) by \( 90^{\circ} \) anticlockwise is given by the transformation:
\[
w_1 = i \cdot z_1 = i \cdot (5 + 4i) = -4 + 5i
\]
For \( w_2 \), the rotation is clockwise by \( 90^{\circ} \). The rotation of a complex number \( z = x + yi \) by \( 90^{\circ} \) clockwise is given by the transformation:
\[
w_2 = -i \cdot z_2 = -i \cdot (3 + 5i) = 5 + 3i
\]
Now, we need to compute the difference \( w_1 - w_2 \):
\[
w_1 - w_2 = (-4 + 5i) - (5 + 3i) = -4 - 5 + (5 - 3)i = -9 + 2i
\]
The principal argument \( \theta \) of a complex number \( z = x + yi \) is given by:
\[
\theta = \tan^{-1}\left( \frac{y}{x} \right)
\]
Thus, for \( w_1 - w_2 = -9 + 2i \):
\[
\theta = \tan^{-1}\left( \frac{2}{-9} \right)
\]
Since \( w_1 - w_2 \) lies in the second quadrant, the principal argument is:
\[
\text{Principal Argument} = \pi + \tan^{-1}\left( \frac{2}{9} \right)
\]
Thus, the correct option is \( \pi - \tan^{-1}\left( \frac{8}{9} \right) \).