Question:

Arrange the following in order of increasing mass :
(i) 1 mole of N2, (ii) 0.5 mole of O3, (iii) \(3.011×10^{23}\) molecules of O2, (iv) 0.5 gram atom of O2

Updated On: Feb 15, 2024
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  • iv<i<iii<ii
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  • i<iii<ii<iv
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The Correct Option is A

Solution and Explanation

The mass of the substance is calculated by multiplying the number of moles of the substance by its molar mass.

For example, the mass of O3 can be found as follows: Mass of O3 = 0.5 moles × 48 g/mol = 24 g

II) One gram atom is equivalent to one mole. Thus, the mass of oxygen (O) is determined by multiplying the number of moles by its molar mass.

For instance, the mass of O in the context could be calculated like this: Mass of O = 0.5 moles × 16 g/mol = 8 g

III) The relationship between moles and molecules is that 1 mole is equal to 6.022 × 10^23 molecules. Consequently, the number of moles of O2 can be determined by dividing the given number of molecules by Avogadro's number.

As an illustration, the moles of O2 can be calculated as follows: Moles of O2 = 6.022×10233.011×10233.011×10236.022×1023​ = 0.5 moles

The mass of O2 can then be found: Mass of O2 = 0.5 moles × 32 g/mol = 16 g

IV) The volume occupied by 1 mole of a gas at NTP (Normal Temperature and Pressure) is 22.4 L. By using this information, the number of moles of CO2 can be calculated based on the given volume.

For instance, the moles of CO2 can be determined as follows: Moles of CO2 = 22.45.65.622.4​ = 0.25 moles

The mass of CO2 can then be calculated: Mass of CO2 = 0.25 moles × 44 g/mol = 11 g

The correct answer is option (A): iv<iii<ii<i

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Concepts Used:

Stoichiometry

Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products, leading to the insight that the relations among quantities of reactants and products typically form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined, then the amount of the other reactants can also be calculated.

Stoichiometry helps us determine how much substance is needed or is present. Things that can be measured are;

  1. Reactants and Products mass
  2. Molecular weight
  3. Chemical equations
  4. Formulas

​​Stoichiometric Coefficient

The Stoichiometric coefficient of any given component is the number of molecules and/or formula units that participate in the reaction as written.

Mole Ratios

The mass of one mole of a substance in grams is called molar mass. The molar mass of one mole of a substance is numerically equal to the atomic/molecular formula mass.