1. Efficiency of a Carnot engine: \[ \eta = 1 - \frac{T_{\text{sink}}}{T_{\text{source}}}. \]
2. For 50\% efficiency: \[ 0.5 = 1 - \frac{T_{\text{sink}}}{600}. \]
\[ T_{\text{sink}} = 300 \, \text{K}. \]
3. For 70\% efficiency: \[ 0.7 = 1 - \frac{300}{T_{\text{source}}}. \]
\[ \frac{300}{T_{\text{source}}} = 0.3. \]
\[ T_{\text{source}} = \frac{300}{0.3} = 1000 \, \text{K}. \]
Thus, the new temperature of the source is 1000 K. The efficiency of a Carnot engine depends on the temperatures of the heat source and sink. Increasing efficiency requires increasing the temperature of the source while keeping the sink temperature constant.
Match List-I with List-II.
Choose the correct answer from the options given below :
The ratio of the fundamental vibrational frequencies \( \left( \nu_{^{13}C^{16}O} / \nu_{^{12}C^{16}O} \right) \) of two diatomic molecules \( ^{13}C^{16}O \) and \( ^{12}C^{16}O \), considering their force constants to be the same, is ___________ (rounded off to two decimal places).}
A heat pump, operating in reversed Carnot cycle, maintains a steady air temperature of 300 K inside an auditorium. The heat pump receives heat from the ambient air. The ambient air temperature is 280 K. Heat loss from the auditorium is 15 kW. The power consumption of the heat pump is _________ kW (rounded off to 2 decimal places).
A molecule with the formula $ \text{A} \text{X}_2 \text{Y}_2 $ has all it's elements from p-block. Element A is rarest, monotomic, non-radioactive from its group and has the lowest ionization energy value among X and Y. Elements X and Y have first and second highest electronegativity values respectively among all the known elements. The shape of the molecule is:
A transition metal (M) among Mn, Cr, Co, and Fe has the highest standard electrode potential $ M^{n}/M^{n+1} $. It forms a metal complex of the type $[M \text{CN}]^{n+}$. The number of electrons present in the $ e $-orbital of the complex is ... ...
Consider the following electrochemical cell at standard condition. $$ \text{Au(s) | QH}_2\text{ | QH}_X(0.01 M) \, \text{| Ag(1M) | Ag(s) } \, E_{\text{cell}} = +0.4V $$ The couple QH/Q represents quinhydrone electrode, the half cell reaction is given below: $$ \text{QH}_2 \rightarrow \text{Q} + 2e^- + 2H^+ \, E^\circ_{\text{QH}/\text{Q}} = +0.7V $$
0.1 mol of the following given antiviral compound (P) will weigh .........x $ 10^{-1} $ g.
Consider the following equilibrium, $$ \text{CO(g)} + \text{H}_2\text{(g)} \rightleftharpoons \text{CH}_3\text{OH(g)} $$ 0.1 mol of CO along with a catalyst is present in a 2 dm$^3$ flask maintained at 500 K. Hydrogen is introduced into the flask until the pressure is 5 bar and 0.04 mol of CH$_3$OH is formed. The $ K_p $ is ...... x $ 10^7 $ (nearest integer).
Given: $ R = 0.08 \, \text{dm}^3 \, \text{bar} \, \text{K}^{-1} \, \text{mol}^{-1} $
Assume only methanol is formed as the product and the system follows ideal gas behavior.
Thermodynamics in physics is a branch that deals with heat, work and temperature, and their relation to energy, radiation and physical properties of matter.
A thermodynamic system is a specific portion of matter with a definite boundary on which our attention is focused. The system boundary may be real or imaginary, fixed or deformable.
There are three types of systems:
A system undergoes a thermodynamic process when there is some energetic change within the system that is associated with changes in pressure, volume and internal energy.
There are four types of thermodynamic process that have their unique properties, and they are:
The Zeroth law of thermodynamics states that if two bodies are individually in equilibrium with a separate third body, then the first two bodies are also in thermal equilibrium with each other.
The First law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes, distinguishing three kinds of transfer of energy, as heat, as thermodynamic work, and as energy associated with matter transfer, and relating them to a function of a body's state, called internal energy.
The Second law of thermodynamics is a physical law of thermodynamics about heat and loss in its conversion.
Third law of thermodynamics states, regarding the properties of closed systems in thermodynamic equilibrium: The entropy of a system approaches a constant value when its temperature approaches absolute zero.