To solve the problem, we need to calculate the work done by an ideal gas expanding from 2 L to 6 L at constant pressure of 2 atm.
1. Formula for Work Done at Constant Pressure:
The work done $W$ by a gas during expansion or compression at constant pressure is given by:
$ W = P \Delta V = P (V_f - V_i) $
2. Given Data:
Initial volume, $V_i = 2\, L = 2 \times 10^{-3} \, m^3$ (since $1\,L = 10^{-3} \, m^3$)
Final volume, $V_f = 6\, L = 6 \times 10^{-3} \, m^3$
Pressure, $P = 2\, atm = 2 \times 1.013 \times 10^5\, Pa = 2.026 \times 10^5\, Pa$
3. Calculating Change in Volume:
$ \Delta V = V_f - V_i = (6 - 2) \times 10^{-3} = 4 \times 10^{-3} \, m^3 $
4. Calculating Work Done:
$ W = P \times \Delta V = 2.026 \times 10^5 \times 4 \times 10^{-3} = 810.4 \, J $
Final Answer:
The work done by the gas is $ {810.4\, J} $.
Standard entropies of \(X_2\), \(Y_2\) and \(XY_5\) are 70, 50, and 110 J \(K^{-1}\) mol\(^{-1}\) respectively. The temperature in Kelvin at which the reaction \[ \frac{1}{2} X_2 + \frac{5}{2} Y_2 \rightarrow XY_5 \quad \Delta H = -35 \, {kJ mol}^{-1} \] will be at equilibrium is (nearest integer):