Explain why
(a) Two bodies at different temperatures T1 and T2 if brought in thermal contact do not necessarily settle to the mean temperature \(\frac{(T1 + T2 )}{2}\).
(b) The coolant in a chemical or a nuclear plant (i.e., the liquid used to prevent the different parts of a plant from getting too hot) should have high specific heat.
(c) Air pressure in a car tyre increases during driving.
(d) The climate of a harbour town is more temperate than that of a town in a desert at the same latitude.
A cylinder with a movable piston contains 3 moles of hydrogen at standard temperature and pressure. The walls of the cylinder are made of a heat insulator, and the piston is insulated by having a pile of sand on it. By what factor does the pressure of the gas increase if the gas is compressed to half its original volume?
Two cylinders A and B of equal capacity are connected to each other via a stopcock. A contains a gas at standard temperature and pressure. B is completely evacuated. The entire system is thermally insulated. The stopcock is suddenly opened. Answer the following :
(a) What is the final pressure of the gas in A and B ?
(b) What is the change in internal energy of the gas ?
(c) What is the change in the temperature of the gas ?
Two cylinders A and B of equal capacity are connected to each other via a stopcock. A contains a gas at standard temperature and pressure. B is completely evacuated. The entire system is thermally insulated. The stopcock is suddenly opened. Answer the following 1) What is the final pressure of the gas in A and B? 2) What is the change in internal energy of the gas? 3) What is the change in the temperature of the gas?
A thermodynamic system is taken from an original state to an intermediate state by the linear process shown in Fig. (11.13).
Its volume is then reduced to the original value from E to F by an isobaric process. Calculate the total work done by the gas from D to E to F
Figure 12.8 shows plot of \(\frac{PV}{T}\) versus P for 1.00×10–3 kg of oxygen gas at two different temperatures.
(a) What does the dotted plot signify?
(b) Which is true: T1>T2 or T1<T2 ?
(c) What is the value of \(\frac{PV}{T}\) where the curves meet on the y-axis?
(d) If we obtained similar plots for \(1.00×10^–3\) kg of hydrogen, would we get the same value of \(\frac{PV}{T}\) at the point where the curves meet on the y-axis? If not, what mass of hydrogen yields the same value of \(\frac{PV}{T}\) (for low pressure high temperature region of the plot) ? (Molecular mass of H2 = 2.02 u, of O2 = 32.0 u, R = 8.31 J mo1–1 K–1.)