Among the given ions, \( \text{F}^{-} \) has the largest size because it is an anion with a greater number of electrons than protons, causing the electron cloud to expand. \( \text{Na}^{+} \), \( \text{Mg}^{2+} \), and \( \text{Al}^{3+} \) are cations, and the higher the charge, the smaller the ionic radius due to increased attraction between the nucleus and electrons.