The standard enthalpy and standard entropy of decomposition of \( N_2O_4 \) to \( NO_2 \) are 55.0 kJ mol\(^{-1}\) and 175.0 J/mol respectively. The standard free energy change for this reaction at 25°C in J mol\(^{-1}\) is (Nearest integer)
An ideal gas initially at 0°C temperature, is compressed suddenly to one fourth of its volume. If the ratio of specific heat at constant pressure to that at constant volume is \( \frac{3}{2} \), the change in temperature due to the thermodynamics process is K.
Match the List-I with List-II
Choose the correct answer from the options given below:
The effect of temperature on the spontaneity of reactions are represented as: Which of the following is correct?
For the thermal decomposition of \( N_2O_5(g) \) at constant volume, the following table can be formed, for the reaction mentioned below: \[ 2 N_2O_5(g) \rightarrow 2 N_2O_4(g) + O_2(g) \] Given: Rate constant for the reaction is \( 4.606 \times 10^{-2} \text{ s}^{-1} \).
Let \( T_r \) be the \( r^{\text{th}} \) term of an A.P. If for some \( m \), \( T_m = \dfrac{1}{25} \), \( T_{25} = \dfrac{1}{20} \), and \( \displaystyle\sum_{r=1}^{25} T_r = 13 \), then \( 5m \displaystyle\sum_{r=m}^{2m} T_r \) is equal to: