Three conductors of same length having thermal conductivity \(k_1\), \(k_2\), and \(k_3\) are connected as shown in figure. Area of cross sections of 1st and 2nd conductor are same and for 3rd conductor it is double of the 1st conductor. The temperatures are given in the figure. In steady state condition, the value of θ is ________ °C. (Given: \(k_1\) = 60 Js⁻¹m⁻¹K⁻¹,\(k_2\) = 120 Js⁻¹m⁻¹K⁻¹, \(k_3\) = 135 Js⁻¹m⁻¹K⁻¹) 
A(g) $ \rightarrow $ B(g) + C(g) is a first order reaction.
The reaction was started with reactant A only. Which of the following expression is correct for rate constant k ?
$\mathrm{KMnO}_{4}$ acts as an oxidising agent in acidic medium. ' X ' is the difference between the oxidation states of Mn in reactant and product. ' Y ' is the number of ' d ' electrons present in the brown red precipitate formed at the end of the acetate ion test with neutral ferric chloride. The value of $\mathrm{X}+\mathrm{Y}$ is _______ .