The molecular orbitals formed from 2s and 2p atomic orbitals are as follows:
\(• Two\ molecular\ orbitals\ of\ 2s\ and\ σ ∗2s\)
\(• Six\ molecular\ orbitals\ of\ 2p: σ2pz, σ ∗2pz, π2px, π2py, π ∗2px, π ∗2py.\)
Thus, the total number of molecular orbitals formed is 8.
Which of the following statement is true with respect to H\(_2\)O, NH\(_3\) and CH\(_4\)?
(A) The central atoms of all the molecules are sp\(^3\) hybridized.
(B) The H–O–H, H–N–H and H–C–H angles in the above molecules are 104.5°, 107.5° and 109.5° respectively.
(C) The increasing order of dipole moment is CH\(_4\)<NH\(_3\)<H\(_2\)O.
(D) Both H\(_2\)O and NH\(_3\) are Lewis acids and CH\(_4\) is a Lewis base.
(E) A solution of NH\(_3\) in H\(_2\)O is basic. In this solution NH\(_3\) and H\(_2\)O act as Lowry-Bronsted acid and base respectively.
Which of the following linear combinations of atomic orbitals will lead to the formation of molecular orbitals in homonuclear diatomic molecules (internuclear axis in z-direction)?
(1) \( 2p_z \) and \( 2p_x \)
(2) \( 2s \) and \( 2p_x \)
(3) \( 3d_{xy} \) and \( 3d_{x^2-y^2} \)
(4) \( 2s \) and \( 2p_z \)
(5) \( 2p_z \) and \( 3d_{x^2-y^2} \)