Question:

The major product of the following reaction is:
6-Phenylhepta-2,4-diene

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In elimination reactions with excess base, the most stable conjugated diene product is favored due to its resonance stability.
Updated On: May 3, 2025
  • 2-Phenylhepta-2,4-diene
  • 6-Phenylhepta-3,5-diene
  • 6-Phenylhepta-2,4-diene
  • 2-Phenylhepta-2,5-diene
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The Correct Option is C

Solution and Explanation

To determine the major product of the given reaction, we need to analyze the structure and reactivity of the compound involved. The question provides us with the compound 6-Phenylhepta-2,4-diene

Step 1: Analyze the structure: The compound is a conjugated diene with phenyl substitution at position 6. It has the structure:

  • Hepta indicates a seven-carbon chain.
  • 2,4-diene implies double bonds at carbons 2 and 4.
  • Phenyl group at position 6.

Step 2: Electrophilic addition reaction: In electrophilic additions, conjugated dienes like hepta-2,4-diene can undergo 1,2-addition (kinetic control) or 1,4-addition (thermodynamic control).

Step 3: Identify stability: Due to conjugation, electrons can delocalize, making certain products more stable. The reaction typically forms a product where the double bonds remain conjugated, as seen with 6-Phenylhepta-2,4-diene. Conjugated double bonds stabilize the molecule through resonance.

OptionProduct Description
2-Phenylhepta-2,4-dienePhenyl group at position 2, different from input structure
6-Phenylhepta-3,5-dienePosition of double bonds is shifted, may not be favored
6-Phenylhepta-2,4-dieneOriginal compound, conjugated diene structure, favored by resonance
2-Phenylhepta-2,5-dieneNon-conjugated, phenyl at position 2

Conclusion: The most stable, resonance-stabilized structure is 6-Phenylhepta-2,4-diene, which is the major product.

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