Standard entropies of \(X_2\), \(Y_2\) and \(XY_5\) are 70, 50, and 110 J \(K^{-1}\) mol\(^{-1}\) respectively. The temperature in Kelvin at which the reaction \[ \frac{1}{2} X_2 + \frac{5}{2} Y_2 \rightarrow XY_5 \quad \Delta H = -35 \, {kJ mol}^{-1} \] will be at equilibrium is (nearest integer):
A(g) $ \rightarrow $ B(g) + C(g) is a first order reaction.
The reaction was started with reactant A only. Which of the following expression is correct for rate constant k ?
$\mathrm{KMnO}_{4}$ acts as an oxidising agent in acidic medium. ' X ' is the difference between the oxidation states of Mn in reactant and product. ' Y ' is the number of ' d ' electrons present in the brown red precipitate formed at the end of the acetate ion test with neutral ferric chloride. The value of $\mathrm{X}+\mathrm{Y}$ is _______ .