Question:

The correct order of reactivity in electrophilic substitution reaction of the following compounds is :
no2

Updated On: Nov 19, 2024
  • \( B > C > A > D \)
  • \( D > C > B > A \)
  • \( A > B > C > D \)
  • \( B > A > C > D \)
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The Correct Option is D

Solution and Explanation

The effect of substituents on electrophilic substitution reactions is as follows:

  • \(-\text{CH}_3\) shows \(+M\) and \(+I\).
  • \(-\text{Cl}\) shows \(+M\) and \(-I\) but inductive effect dominates.
  • \(-\text{NO}_2\) shows \(-M\) and \(-I\).

Electrophilic substitution order is based on \( \alpha + M \) and \( +I \), with the highest reactivity for the methyl group. Hence, order is \( B > A > C > D \).

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