When comparing bond dissociation energies:
• Consider bond length: shorter bonds generally have higher bond energy.
• Check for lone pair-lone pair repulsions, which can weaken bonds, as seen in F2.
Cl2
I2
F2
Br2
- Bond dissociation energy is the energy required to break a bond in a molecule. - The bond energy order for halogens is:
\(Cl_2 > Br_2 > F_2 > I_2.\)
- Although F2 has a shorter bond length than Cl2, the bond energy of F2 is lower due to lone pair-lone pair repulsions. - Cl2 has the highest bond dissociation energy as it has the optimal bond length and no significant repulsions.
The cycloalkene (X) on bromination consumes one mole of bromine per mole of (X) and gives the product (Y) in which C : Br ratio is \(3:1\). The percentage of bromine in the product (Y) is _________ % (Nearest integer).
Given:
\[ \text{H} = 1,\quad \text{C} = 12,\quad \text{O} = 16,\quad \text{Br} = 80 \]
In the given figure, the blocks $A$, $B$ and $C$ weigh $4\,\text{kg}$, $6\,\text{kg}$ and $8\,\text{kg}$ respectively. The coefficient of sliding friction between any two surfaces is $0.5$. The force $\vec{F}$ required to slide the block $C$ with constant speed is ___ N.
(Given: $g = 10\,\text{m s}^{-2}$) 
Method used for separation of mixture of products (B and C) obtained in the following reaction is: 
Which of the following best represents the temperature versus heat supplied graph for water, in the range of \(-20^\circ\text{C}\) to \(120^\circ\text{C}\)? 