Propanoic acid to Ethane
1. To convert propanoic acid to ethane, we perform a reduction reaction using a strong reducing agent like LiAlH‚„. The steps are: 1. Reduction of Propanoic acid: Propanoic acid is reduced by lithium aluminum hydride (LiAlH‚„) to ethanol. \[ \text{CH}_3\text{CH}_2\text{COOH} \xrightarrow{\text{LiAlH}_4} \text{CH}_3\text{CH}_2\text{OH} \] 2. Reduction of Ethanol to Ethane: Ethanol is then reduced further by a reducing agent like zinc in the presence of hydrochloric acid (Zn/HCl) to ethane. \[ \text{CH}_3\text{CH}_2\text{OH} \xrightarrow{\text{Zn/HCl}} \text{CH}_3\text{CH}_3 \] Thus, Propanoic acid is first converted to ethanol and then ethanol to ethane.
Complete and balance the following chemical equations: (a) \[ 2MnO_4^-(aq) + 10I^-(aq) + 16H^+(aq) \rightarrow \] (b) \[ Cr_2O_7^{2-}(aq) + 6Fe^{2+}(aq) + 14H^+(aq) \rightarrow \]
Acidified KMnO_4 oxidizes sulphite to:
Which element is a strong reducing agent in +2 oxidation state and why?
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.