Complete and balance the following chemical equations: (a) \[ 2MnO_4^-(aq) + 10I^-(aq) + 16H^+(aq) \rightarrow \] (b) \[ Cr_2O_7^{2-}(aq) + 6Fe^{2+}(aq) + 14H^+(aq) \rightarrow \]
(a) Reaction of permanganate with iodide ions: In an acidic solution, permanganate ions (\(MnO_4^-\)) act as an oxidizing agent and oxidize iodide ions (\(I^-\)) to iodine (\(I_2\)). The balanced equation shows the reduction of permanganate to \(Mn^{2+}\) and the oxidation of iodide to iodine. \[ 2MnO_4^-(aq) + 10I^-(aq) + 16H^+(aq) \rightarrow 2Mn^{2+}(aq) + 5I_2(aq) + 8H_2O(l) \] (b) Reaction of dichromate with iron(II) ions: In an acidic solution, dichromate ions (\(Cr_2O_7^{2-}\)) are reduced to chromium(III) ions (\(Cr^{3+}\)), while iron(II) ions (\(Fe^{2+}\)) are oxidized to iron(III) ions (\(Fe^{3+}\)). \[ Cr_2O_7^{2-}(aq) + 6Fe^{2+}(aq) + 14H^+(aq) \rightarrow 2Cr^{3+}(aq) + 6Fe^{3+}(aq) + 7H_2O(l) \]
Acidified KMnO_4 oxidizes sulphite to:
Which element is a strong reducing agent in +2 oxidation state and why?
Propanoic acid to Ethane
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.