List of practice Questions

What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions. 
  1. F- 
  2. Ar 
  3. Mg2+ 
  4. Rb+
Consider the following species: N3- , O2-, F-, Na+, Mg2+ and Al3+ 
  1. What is common in them? 
  2. Arrange them in the order of increasing ionic radii.
Explain why cations are smaller and anions larger in radii than their parent atoms?
Anything that influences the valence electrons will affect the chemistry of the element. Which one of the following factors does not affect the valence shell?

The size of isoelectronic species - F-, Ne and Na+ is affected by

What are the various factors due to which the ionization enthalpy of the main group elements tends to decrease down a group?
The first ionization enthalpy values (in kJmol-1 ) of group 13 elements are :
BAlGaInTl
801577579558589
How would you explain this deviation from the general trend?
Which of the following pairs of elements would have a more negative electron gain enthalpy? 
  1. O or F 
  2. F or Cl
Dinitrogen and dihydrogen react with each other to produce ammonia according to the following chemical equation: \(N_2 (g) + H_2 (g) → 2NH_3 (g)\)
  1. Calculate the mass of ammonia produced if 2.00 × 103 g dinitrogen reacts with 1.00 × 103 g of dihydrogen.
  2. Will any of the two reactants remain unreacted?
  3. If yes, which one and what would be its mass?
How are 0.50 mol Na2CO3 and 0.50 M Na2CO3 different?
If 10 volumes of dihydrogen gas reacts with five volumes of dioxygen gas, how many volumes of water vapour would be produced?
Name three groups of plants that bear archegonia. Briefly describe the life cycle of any one of them.
(i) Calculate the number of electrons which will together weigh one gram.
(ii) Calculate the mass and charge of one mole of electrons.
Convert the following into basic units:
  1. 28.7 pm
  2. 15.15 pm
  3. 25365 mg
How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium?
Among the second period elements the actual ionization enthalpies are in the order 
Li < B < Be < C < O < N < F < Ne. 
Explain why 
  1. Be has higher ΔiH than B
  2. O has lower ΔiH than N and F?
Energy of an electron in the ground state of the hydrogen atom is -2.18 x 10-18  J. Calculate the ionization enthalpy of atomic hydrogen in terms of J mol-1  .
In a reaction \(A + B_2 → AB_2\) Identify the limiting reagent, if any, in the following reaction mixtures.
  1. 300 atoms of A + 200 molecules of B
  2. 2 mol A + 3 mol B
  3. 100 atoms of A + 100 molecules of B
  4. 5 mol A + 2.5 mol B
  5. 2.5 mol A + 5 mol B
If the speed of light is 3.0×108 ms–1, calculate the distance covered by light in 2.00 ns.
What is the significance of the terms - 'isolated gaseous atom' and 'ground state' while defining the ionization enthalpy and electron gain enthalpy?
Hint: Requirements for comparison purposes.
Would you expect the second electron gain enthalpy of O as positive, more negative or less negative than the first? Justify your answer.
What is the basic difference between the terms electron gain enthalpy and electronegativity?
How would you react to the statement that the electronegativity of N on Pauling scale is 3.0 in all the nitrogen compounds?

Differentiate between the following:-
(i) red algae and brown algae
(ii) liverworts and moss
(iii) homosporous and heterosporous pteridophyte

Describe the theory associated with the radius of an atom as it 
  1. gains an electron 
  2. loses an electro