In heteronuclear molecules, polarization arises due to a difference in the electronegativities of the constituents of atoms. As a result, one end of the molecule acquires a positive charge while the other end becomes negative. Hence, a molecule is said to possess a dipole.
The product of the magnitude of the charge and the distance between the centres of positive-negative charges is called the dipole moment \((\mu)\) of the molecule. It is a vector quantity and is represented by an arrow with its tail at the positive centre and head pointing towards a negative centre.
Dipole moment \((\mu)\) = charge \((Q)\) x distance of separation \((r)\)
The SI unit of a dipole moment is '\(esu\)'.
\(1 \;esu\) = \(3.335 \times 10^{ -30}\; cm\)
Dipole moment is the measure of the polarity of a bond. It is used to differentiate between polar and non-polar bonds since all non-polar molecules (e.g. \(H_2\), \(O_2\)) have zero dipole moments. It is also helpful in calculating the percentage ionic character of a molecule.
Such a group of atoms is called a molecule. Obviously, there must be some force that holds these constituent atoms together in the molecules. The attractive force which holds various constituents (atoms, ions, etc.) together in different chemical species is called a chemical bond.
There are 4 types of chemical bonds which are formed by atoms or molecules to yield compounds.