Question:

Write the significance/applications of dipole moment.

Updated On: Nov 9, 2023
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Solution and Explanation

In heteronuclear molecules, polarization arises due to a difference in the electronegativities of the constituents of atoms. As a result, one end of the molecule acquires a positive charge while the other end becomes negative. Hence, a molecule is said to possess a dipole.

The product of the magnitude of the charge and the distance between the centres of positive-negative charges is called the dipole moment \((\mu)\) of the molecule. It is a vector quantity and is represented by an arrow with its tail at the positive centre and head pointing towards a negative centre.
Dipole moment \((\mu)\) = charge \((Q)\) x distance of separation \((r)\) 
The SI unit of a dipole moment is '\(esu\)'. 
\(1 \;esu\) = \(3.335 \times 10^{ -30}\; cm\) 

Dipole moment is the measure of the polarity of a bond. It is used to differentiate between polar and non-polar bonds since all non-polar molecules (e.g. \(H_2\)\(O_2\)) have zero dipole moments. It is also helpful in calculating the percentage ionic character of a molecule.
Dipole moment of polar and non-polar bonds

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Concepts Used:

Chemical Bonding and Molecular Structure

Such a group of atoms is called a molecule. Obviously, there must be some force that holds these constituent atoms together in the molecules. The attractive force which holds various constituents (atoms, ions, etc.) together in different chemical species is called a chemical bond.

Types of Chemical Bonds:

There are 4 types of chemical bonds which are formed by atoms or molecules to yield compounds. 

  • Ionic Bonds - Ionic bonding is a type of chemical bonding which involves a transfer of electrons from one atom or molecule to another.
  • Covalent Bonds - Compounds that contain carbon commonly exhibit this type of chemical bonding. 
  • Hydrogen Bonds -  It is a type of polar covalent bonding between oxygen and hydrogen wherein the hydrogen develops a partial positive charge
  • Polar Bonds - In Polar Covalent chemical bonding, electrons are shared unequally since the more electronegative atom pulls the electron pair closer to itself and away from the less electronegative atom.

Factors Affecting Bond Enthalpy in Chemical Bonding:

  • Size of the Atom
  • Multiplicity of Bonds
  • Number of Lone Pair of Electrons Present
  • Bond Angle