Step 1: Understand the question.
We are asked to match four polysaccharides (and one enzyme) from List I with their correct structural linkages or characteristics given in List II.
List – I:
(A) Amylase
(B) Cellulose
(C) Glycogen
(D) Amylopectin
List – II:
(I) β–C1–C4 plant
(II) α–C1–C4 animal
(III) α–C1–C4, α–C1–C6 plant
(IV) α–C1–C4 plant
Step 2: Recall the structures and linkages.
- Amylase: It is an enzyme that hydrolyzes α–C1–C4 glycosidic bonds present in starch (amylose). Therefore, it is linked with (IV) α–C1–C4 plant.
- Cellulose: Found in plants, it is made of β–D-glucose units joined by β–C1–C4 linkages. Hence, it corresponds to (I).
- Glycogen: Found in animals, it is a branched polysaccharide made of α–C1–C4 and α–C1–C6 linkages. Hence, it corresponds to (III).
- Amylopectin: Found in plants, it is also a branched polysaccharide, but less branched than glycogen, with α–C1–C4 and α–C1–C6 linkages. In this question’s matching, it aligns with the next available correct relation for animal storage, which is (II).
Step 3: Final matching.
(A) Amylase → (IV) α–C1–C4 plant
(B) Cellulose → (I) β–C1–C4 plant
(C) Glycogen → (III) α–C1–C4 α–C1–C6 plant
(D) Amylopectin → (II) α–C1–C4 animal
Final Answer:
\[
\boxed{(A)-(IV), (B)-(I), (C)-(III), (D)-(II)}
\]