Which of the following statements is not true about glucose?
It does not give Schiff's test.
Step 1: Understanding glucose's properties. Glucose is an aldose (option A) and forms n-hexane on heating with HI (option B). It can exist in the furanose form (option C) as well.
Step 2: Schiff's test. Glucose, being an aldehyde, will give a positive Schiff's test, which detects aldehydes.
Step 3: Conclusion. Thus, the statement that glucose does not give Schiff's test is incorrect, corresponding to option (D). \vspace{10pt}
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.