Let's break down each term and match it with the correct option:
1.
Nucleophile:
A nucleophile is a species that donates an electron.
Hence, \( a \) matches with (iv).
2.
Electrophile:
An electrophile is a species that accepts an electron.
Therefore, \( b \) matches with (iii).
3.
Carbocation:
A carbocation is a positively charged carbon species and is planar and sp\(^2\) hybridized.
Hence, \( c \) matches with (ii).
4.
Carbanion:
A carbanion is a negatively charged carbon species and typically has a tetrahedral shape.
Therefore, \( d \) matches with (i).
Thus, the correct match is:
\[
a(iv), b(iii), c(ii), d(i)
\]
Final Answer: The correct option is (2).