Step 1: Analyze each set.
\( S_1 \) includes symmetric matrices, so elements above the diagonal determine the matrix. With 5 choices for each, and 6 such positions: \[ |S_1| = 5^6 \] \( S_2 \) includes skew-symmetric matrices, where non-diagonal elements are independent, and diagonal elements must be 0 (which are not in \( S \)), invalidating \( S_2 \). Thus: \[ |S_2| = 0 \] \( S_3 \) must balance the trace to be zero. Choosing two elements freely allows the third to be determined: \[ |S_3| = 5^2 \times (\text{number of valid third elements}) \]
Step 2: Calculate the union of sets.
Using the inclusion-exclusion principle, find \( n(S_1 \cup S_2 \cup S_3) \): \[ n(S_1 \cup S_2 \cup S_3) = |S_1| + |S_2| + |S_3| - (\text{intersections}) = 125 \]
From the magnetic behaviour of \([NiCl_4]^{2-}\) (paramagnetic) and [Ni\((CO)_4\)] (diamagnetic), choose the correct geometry and oxidation state.
Given below are two statements. One is labelled as Assertion (A) and the other is labelled as Reason (R):
Assertion (A): In an insulated container, a gas is adiabatically shrunk to half of its initial volume. The temperature of the gas decreases.
Reason (R): Free expansion of an ideal gas is an irreversible and an adiabatic process.
In the light of the above statements, choose the correct answer from the options given below: