Question:

Group-13 elements react with O2 in amorphous form to form oxides of type M2O3 (M = element). Which among the following is the most basic oxide?

Updated On: Mar 21, 2025
  • Al2O3

  • Tl2O3

  • Ga2O3

  • B2O3

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The Correct Option is B

Solution and Explanation

Group 13 Oxide Basicity 

As we move down Group 13, the metallic character increases, and hence the electropositive character increases. As electropositivity increases, the basicity of the oxides increases.

The order of basicity for Group 13 oxides is \( \text{B}_2\text{O}_3 < \text{Al}_2\text{O}_3 < \text{Ga}_2\text{O}_3 < \text{In}_2\text{O}_3 < \text{Tl}_2\text{O}_3 \).

Conclusion:

\( \text{Tl}_2\text{O}_3 \) is the most basic oxide.

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