Question:

Equal volumes of aqueous solution of 0.1 M HCl and 0.2 M H2SO4 are mixed. The concentration of H+ ions in the resulting solution is:

Updated On: Jan 10, 2025
  • 0.15 M
  • 0.30 M
  • 0.10 M
  • 0.25 M
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The Correct Option is D

Solution and Explanation

  • HCl is a monoprotic acid, so 0.1 M HCl provides 0.1 M H+ ions.
  • H2SO4 is a diprotic acid, so 0.2 M H2SO4 provides 2 × 0.2 = 0.4 M H+ ions.

When equal volumes of the two solutions are mixed, the total volume doubles, and the concentration of each acid is halved:

New concentration of HCl = \(\frac{0.1}{2} = 0.05 \text{M H}^+\)

New concentration of H2SO4 = \(\frac{0.4}{2} = 0.2 \text{M H}^+\)

The total H+ concentration is:

\( 0.05 \text{M} + 0.2 \text{M} = 0.25 \text{M} \)

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