For borax bead test:
• In the oxidizing flame, metal ions form metaborates, which produce characteristic colours.
• The observed colour is a key indicator of the specific metal ion present.
\(Cu(BO_2)_2\)
\(Cu_3B_2\)
Borax Bead Test:
1. Definition: The borax bead test is a qualitative test used to identify metal ions based on the colour imparted to the bead in the oxidizing or reducing flame.
In this test, borax (\(\text{Na}_2\text{B}_4\text{O}_7 \cdot 10\text{H}_2\text{O}\)) decomposes to form sodium metaborate (\(\text{NaBO}_2\)) and boric anhydride (\(\text{B}_2\text{O}_3\)) when heated:
\[\text{Na}_2\text{B}_4\text{O}_7 \xrightarrow{\Delta} 2\text{NaBO}_2 + \text{B}_2\text{O}_3.\]
2. Reaction with \(\text{CuSO}_4\): Copper ions react with boric anhydride (\(\text{B}_2\text{O}_3\)) to form copper metaborate (\(\text{Cu(BO}_2)_2\)) in the oxidizing flame:
\[\text{CuSO}_4 + \text{B}_2\text{O}_3 \rightarrow \text{Cu(BO}_2)_2 + \text{SO}_3.\]
3.Observation: \(\text{Cu(BO}_2)_2\) is responsible for the blue-green colour observed in the oxidizing flame.
Final Answer: \((3)\) \(\mathbf{Cu(BO}_2)_2\).
According to the generally accepted definition of the ideal solution there are equal interaction forces acting between molecules belonging to the same or different species. (This is equivalent to the statement that the activity of the components equals the concentration.) Strictly speaking, this concept is valid in ecological systems (isotopic mixtures of an element, hydrocarbons mixtures, etc.). It is still usual to talk about ideal solutions as limiting cases in reality since very dilute solutions behave ideally with respect to the solvent. This law is further supported by the fact that Raoult’s law empirically found for describing the behaviour of the solvent in dilute solutions can be deduced thermodynamically via the assumption of ideal behaviour of the solvent.
Answer the following questions:
(a) Give one example of miscible liquid pair which shows negative deviation from Raoult’s law. What is the reason for such deviation?
(b) (i) State Raoult’s law for a solution containing volatile components.
OR
(ii) Raoult’s law is a special case of Henry’s law. Comment.
(c) Write two characteristics of an ideal solution.