Question:

Which of the following aqueous solutions will have the highest osmotic pressure ?

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More ions → higher $i$ → greater osmotic pressure.
  • 1% KCl
  • 1% glucose
  • 1% urea
  • 1% CaCl$_2$
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The Correct Option is D

Solution and Explanation

Osmotic pressure is directly proportional to the number of particles (van't Hoff factor, $i$). CaCl$_2$ dissociates into 3 ions (1 Ca$^{2+}$ + 2 Cl$^-$) while KCl gives 2 ions, and glucose/urea don’t ionise. So, CaCl$_2$ gives the highest number of particles and thus the highest osmotic pressure.
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