Question:

What is meant by negative deviation from Raoult’s law? Give an example. What type of azeotrope is formed by negative deviation?

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Stronger interactions → negative deviation → max boiling azeotrope.
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Solution and Explanation

Negative deviation occurs when the observed vapour pressure of a solution is
lower than that predicted by Raoult’s law.
This is due to stronger A–B intermolecular attractions than A–A or B–B.
Example: acetone and chloroform mixture.
Such mixtures form maximum boiling azeotropes.
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