Question:
Correct solubility order of AgF, AgCl, AgBr, AgI in water is:
Correct solubility order of AgF, AgCl, AgBr, AgI in water is:
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The solubility of silver halides decreases as the size of the halide ion increases due to the balance of lattice energy and hydration energy.
Updated On: Jan 10, 2025
- AgF<AgCl>AgBr>AgI
- AgI<AgBr<AgCl<AgF
- AgF<AgCl<AgBr<AgI
- AgCl>AgBr>AgF>AgI
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The Correct Option is B
Solution and Explanation
The solubility of silver halides in water decreases as the size of the halide ion increases. This is because:
- Larger halide ions (e.g., I−) have lower lattice energy compared to smaller halide ions (e.g., F−).
- The lattice energy dominates over the hydration energy, making the solubility lower for larger ions.
Therefore, the solubility order is: AgF>AgCl>AgBr>AgI.
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