
| Number of intermediates | Number of Activated complexes | Rate determining step |
| 2 | 3 | II |
| Number of intermediates | Number of Activated complexes | Rate determining step |
| 2 | 3 | III |
| Number of intermediates | Number of Activated complexes | Rate determining step |
| 3 | 2 | II |
| Number of intermediates | Number of Activated complexes | Rate determining step |
| 2 | 3 | I |
Therefore, the correct option is (1): 2 intermediates, 3 activated complexes, and step II as the rate-determining step.
Calculate the potential for half-cell containing 0.01 M K\(_2\)Cr\(_2\)O\(_7\)(aq), 0.01 M Cr\(^{3+}\)(aq), and 1.0 x 10\(^{-4}\) M H\(^+\)(aq).

Let \( a \in \mathbb{R} \) and \( A \) be a matrix of order \( 3 \times 3 \) such that \( \det(A) = -4 \) and \[ A + I = \begin{bmatrix} 1 & a & 1 \\ 2 & 1 & 0 \\ a & 1 & 2 \end{bmatrix} \] where \( I \) is the identity matrix of order \( 3 \times 3 \).
If \( \det\left( (a + 1) \cdot \text{adj}\left( (a - 1) A \right) \right) \) is \( 2^m 3^n \), \( m, n \in \{ 0, 1, 2, \dots, 20 \} \), then \( m + n \) is equal to:
Rate law for a reaction between $A$ and $B$ is given by $\mathrm{R}=\mathrm{k}[\mathrm{A}]^{\mathrm{n}}[\mathrm{B}]^{\mathrm{m}}$. If concentration of A is doubled and concentration of B is halved from their initial value, the ratio of new rate of reaction to the initial rate of reaction $\left(\frac{\mathrm{r}_{2}}{\mathrm{r}_{1}}\right)$ is