The reaction proceeds via an \( S_N1 \) mechanism where the chlorine group leaves, forming a carbocation.
After the formation of the carbocation, a 1,2-hydride shift occurs to stabilize the carbocation, resulting in a more stable tertiary carbocation.
Subsequent attack by hydroxide ion (\( \text{OH}^- \)) leads to the formation of the major product:
The major product is a tertiary alcohol.
For a reaction, \[ {N}_2{O}_5(g) \rightarrow 2{NO}_2(g) + \frac{1}{2} {O}_2(g) \] in a constant volume container, no products were present initially. The final pressure of the system when 50% of the reaction gets completed is:
In Carius method for estimation of halogens, 180 mg of an organic compound produced 143.5 mg of AgCl. The percentage composition of chlorine in the compound is ___________%. [Given: Molar mass in g mol\(^{-1}\) of Ag = 108, Cl = 35.5]
Match the following List-I with List-II and choose the correct option: List-I (Compounds) | List-II (Shape and Hybridisation) (A) PF\(_{3}\) (I) Tetrahedral and sp\(^3\) (B) SF\(_{6}\) (III) Octahedral and sp\(^3\)d\(^2\) (C) Ni(CO)\(_{4}\) (I) Tetrahedral and sp\(^3\) (D) [PtCl\(_{4}\)]\(^{2-}\) (II) Square planar and dsp\(^2\)
Let A be a 3 × 3 matrix such that \(\text{det}(A) = 5\). If \(\text{det}(3 \, \text{adj}(2A)) = 2^{\alpha \cdot 3^{\beta} \cdot 5^{\gamma}}\), then \( (\alpha + \beta + \gamma) \) is equal to: