Question:

Compare boiling point of given solutions:
(i) \( 10^{-4} \, \text{M NaCl} \)>(ii) \( 10^{-3} \, \text{M NaCl} \)>(iii) \( 10^{-2} \, \text{M NaCl} \)>(iv) \( 10^{-4} \, \text{M urea} \)
(iii) \( 10^{-2} \, \text{M NaCl} \)>(ii) \( 10^{-3} \, \text{M NaCl} \)>(i) \( 10^{-4} \, \text{M NaCl} \)>(iv) \( 10^{-4} \, \text{M urea} \)
(ii) \( 10^{-3} \, \text{M NaCl} \)>(i) \( 10^{-4} \, \text{M NaCl} \)>(iii) \( 10^{-2} \, \text{M NaCl} \)>(iv) \( 10^{-4} \, \text{M urea} \)
(iii) \( 10^{-2} \, \text{M NaCl} \)>(ii) \( 10^{-3} \, \text{M NaCl} \)>(i) \( 10^{-4} \, \text{M NaCl} \)>(iv) \( 10^{-4} \, \text{M urea} \)

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Boiling point elevation is directly related to the molality of the solution and the number of dissociated particles.
Updated On: Mar 24, 2025
  • \( i>ii>iii>iv \)
  • \( iii>ii>i>iv \)
  • \( ii>i>iii>iv \)
  • \( iii>ii>i>iv \)
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The Correct Option is B

Solution and Explanation

Higher the elevation in boiling point, higher will be the boiling point
\( \Delta T_b \propto i \times m \)
For urea \( i = 1 \)
For NaCl \( i = 2 \)
Boiling point order: III>II>I>IV
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